15-5 PH Stainless Steel
metalmartensitic precipitation-hardened stainless steel
Composition — UNS S15500 / ASTM A693 / AMS 5659
| Element | Min % | Max % | Notes |
|---|---|---|---|
| Fe | bal. | balance | |
| Cr | 14.00 | 15.500 | Lower Cr vs. 17-4 PH (15.5–17.5%) — primary corrosion resistance via Cr₂O₃ passivation |
| Ni | 3.50 | 5.500 | Austenite stabiliser; similar to 17-4 PH |
| Cu | 2.50 | 4.500 | Precipitation hardening agent — Cu-rich precipitates form on ageing |
| Nb | 0.15 | 0.450 | CB (Columbium/Niobium) — forms NbC carbides; controls grain size and reduces sensitisation. Distinguishes 15-5 PH from 17-4 PH (which uses Nb also, but different ratio) |
| Mn | — | 1.000 | |
| Si | — | 1.000 | |
| C | — | 0.070 | |
| P | — | 0.040 | |
| S | — | 0.030 |
Mechanical & thermal properties — 4 conditions
| Property | LPBF as-built (XY) | LPBF + H900 (480°C / 1h / AC) (XY) — peak strength | LPBF + H900 (Z) | LPBF + H1025 (552°C / 4h / AC) (XY) — balanced |
|---|---|---|---|---|
| Elastic modulus | 190–205 GPa | — | — | — |
| Yield strength (0.2%) | 820–1030 MPa | 1170–1280 MPa | 1020–1180 MPa | 1000–1090 MPa |
| Ultimate tensile strength | 950–1180 MPa | 1280–1380 MPa | 1130–1290 MPa | 1070–1160 MPa |
| Elongation at break | 12.0–26.0 % | 6.0–12.0 % | 4.0–12.0 % | 10.0–18.0 % |
| Fatigue strength | — | 530–720 MPa | — | — |
| Density | 7.78 g/cm³ | — | — | — |
| Relative density | 99.0–99.9 % | — | — | — |
| Thermal conductivity | 13.0–15.2 W/m·K | — | — | — |
| CTE | 10.2–11.4 µm/m·K | — | — | — |
| As-built surface Ra | 7.0–18.0 µm | — | — | — |
Values shown as min–max where a spread is reported, otherwise as typical ± unit. Ranges reflect inter-source variation, not single-sample scatter. All values are for AM-processed specimens unless noted.
Engineering considerations
- Austenite retention management: the most critical process control issue for LPBF 15-5 PH. Measure retained austenite by XRD on witness coupons from every build before accepting parts. Target <5% retained austenite after H900. If >10%, consider cryogenic treatment (-73°C/1h between HT steps) or re-optimise build parameters to reduce cooling rate variation.
- Heat treatment protocol for H900: (a) remove from build plate after stress relief at 650°C/2h in Ar; (b) solution treatment is not required for most applications — go directly to ageing; (c) age at 480°C ±10°C / 1h / air cool. Temperature accuracy is critical — a 10°C increase reduces UTS by ~20 MPa. Calibrate furnace before each batch.
- Machining strategy: machine in over-aged condition (H1150, 621°C/4h) if significant stock removal is needed. H1150 is near-annealed soft condition (~820 MPa UTS, ~1 HRC) — much easier to machine than H900. Re-age to H900 after machining. Final dimensions after re-age will change by <0.05% — account for in tolerance planning.
- Corrosion: passivation per ASTM A380 or ASTM A967 after final machining to maximise corrosion resistance. Avoid contact with chlorides in service — 15-5 PH will pit and stress-corrosion-crack in H900 condition at high chloride concentrations (>100 ppm) and elevated temperature.
- Surface integrity for fatigue: as-built LPBF surface (Ra 10–18 µm) must be machined or finished for fatigue-critical surfaces. Shot peening after machining can introduce beneficial compressive residual stress — increases fatigue limit by 20–30% for H900 condition.
- Phase stability: 15-5 PH is susceptible to sensitisation if held at 400–650°C for extended periods (>100h) — Cr₂₃C₆ precipitates at grain boundaries deplete Cr, reducing corrosion resistance. Avoid prolonged service in this temperature range. H900 service temperature should not exceed 340°C for extended operation.
- Part qualification: for aerospace structural 15-5 PH LPBF parts, use AMS 7008 as a framework (substituting 15-5 PH composition limits) plus OEM-specific property requirements. X-ray CT inspection for internal defects, FPI for surface cracks, and CMM for dimensional verification are standard.
Advantages
- Highest strength of common AM stainless steels — H900 UTS ~1310 MPa vs. 316L ~600–700 MPa
- Good corrosion resistance — better than 410/420 martensitic SS in atmospheric and mild acidic environments
- Simple ageing cycle (480°C/1h) achieves peak H900 from as-built LPBF — no complex solution treatment needed
- Better transverse toughness than 17-4 PH at equivalent strength — lower ferrite content in 15-5 PH vs. 17-4 PH
- Good machinability in aged condition — cuts cleanly with carbide tooling vs. austenitic SS which work-hardens severely
- LPBF parameter set is essentially identical to 17-4 PH — knowledge transfers directly
- Multiple heat-treatment conditions (H900/H925/H1025/H1075/H1150) allow strength-toughness trade-off for each application
- Non-magnetic in as-built state (retained austenite); near-fully magnetic after H900 (fully martensitic)
Limitations
- Austenite retention in LPBF is a key risk: LPBF rapid cooling produces 10–30% retained austenite vs. <5% in wrought. Retained austenite reduces strength and causes property variability. Mitigation: cryogenic treatment (-73°C/1h) before ageing, or accept H900 properties below wrought minimum
- Z-direction H900 UTS may not consistently meet AMS 5659 minimum (1310 MPa) — qualification testing in Z-direction is mandatory
- H900 is brittle at low temperature — Charpy impact energy <14 J at -40°C. Not suitable for cryogenic applications or impact-critical applications in H900
- Corrosion resistance is inferior to 316L in chloride-rich environments — use 316L or super-duplex for marine and offshore
- High hardness in H900 (44 HRC) makes machining difficult — machine in over-aged (H1150) condition if complex machining is needed, then re-age
- Residual stress in LPBF as-built is significant — stress relief before removal from build plate is recommended for complex parts
- No dedicated AM 15-5 PH standard — AMS 7008 (17-4 PH) is used as proxy, adding qualification complexity
- Magnetism: H900 condition is strongly magnetic — may interfere with precision sensors and MRI environments
Typical applications
Industries
Standards & certifications
LPBF-produced 17-4 PH stainless steel for aerospace — directly applicable H900 and H1025 conditions; also used as process reference for 15-5 PH LPBF qualification
AMS 7008 is specifically for 17-4 PH (UNS S17400), but is widely used as qualification framework reference for 15-5 PH LPBF in aerospace until a dedicated 15-5 PH AM standard is published.
NADCAP accreditation for metallic AM parts — required for aerospace flight-critical 15-5 PH parts
Compatible AM processes (1)
Other metal materials
Related calculators
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