maraging steel — tooling grade (ultra-high-strength, precipitation-hardened)

| Element | Min % | Max % | Notes |
|---|---|---|---|
| Ni | 17.00 | 19.000 | High Ni for martensite transformation (no carbon hardening). Ni content controls martensite start temperature (Ms ~155°C for 18Ni-300) |
| Co | 8.50 | 9.500 | Promotes Mo precipitation on ageing by reducing Mo solubility in γ matrix; lowers Ms temperature slightly |
| Mo | 4.50 | 5.200 | Primary age-hardening precipitate Ni₃Mo; also Ni₄Mo. Controls ultimate hardness — 4.5–5.2% Mo is the 18Ni-300 specification |
| Ti | 0.50 | 0.800 | Forms Ni₃Ti precipitates; secondary contribution to peak hardness. Interacts with Al to form ordered Ni₃(Al,Ti) |
| Al | 0.05 |
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| 0.150 |
| Deoxidiser during atomisation; promotes ordered phase formation on ageing |
| Fe | bal. | balance |
| C | — | 0.030 | CRITICAL: must be below 0.03%. Carbon in martensite causes brittleness and reduces toughness. 'Maraging' = martensite + ageing — no carbon hardening involved |
| Mn | — | 0.100 |
| Si | — | 0.100 |
| P | — | 0.010 |
| S | — | 0.010 |
| Zr | — | 0.010 |
| B | — | 0.003 | Grain boundary strengthener; suppresses grain boundary failure during ageing. Critical for fatigue life in injection moulding cyclic service |
| Property | LPBF as-built (XY) — soft martensite | LPBF aged 490°C/6h (XY) — tooling condition | LPBF aged 490°C/6h (Z) | LPBF aged + nitrided surface (tooling production) |
|---|---|---|---|---|
| Elastic modulus | 170–190 GPa | — | — | — |
| Yield strength (0.2%) | 900–1100 MPa | 1900–2080 MPa | 1740–1960 MPa | — |
| Ultimate tensile strength | 1000–1200 MPa | 1960–2150 MPa | 1830–2050 MPa | — |
| Elongation at break | 8.0–16.0 % | 2.0–6.0 % | 1.5–5.0 % | — |
| Hardness (HV) | — | 530–600 HV10 | — | 900–1150 HV0.1 |
| Fatigue strength | — | 700–900 MPa | — | — |
| Density | 7.95–8.05 g/cm³ | — | — | — |
| Thermal conductivity | 16.0–18.5 W/m·K | — | — | — |
| CTE | 10.2–11.2 µm/m·K | — | — | — |
Values shown as min–max where a spread is reported, otherwise as typical ± unit. Ranges reflect inter-source variation, not single-sample scatter. All values are for AM-processed specimens unless noted.